Category: 151-10-0

An article Aromatic Halogenation Using N-Halosuccinimide and PhSSiMe3 or PhSSPh WOS:000471212000079 published article about LEWIS-BASE CATALYSIS; METHYLENE ACETALS; COMBINATION; EFFICIENT; 1,3-DIBROMO-5,5-DIMETHYLHYDANTOIN; BROMOSULFENYLATION; TRANSFORMATION; BROMINATION; PHENOLS; SOLVENT in [Hirose, Yuuka; Yamazaki, Mirai; Nogata, Misa; Nakamura, Akira; Maegawa, Tomohiro] Kindai Univ, Sch Pharmaceut Sci, Osaka 5778502, Japan in 2019, Cited 43. Product Details of 151-10-0. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0

We developed a mild aromatic halogenation reaction using a combination of N-halosuccinimide and PhSSiMe3 or PhSSPh. Less reactive aromatic compounds, such as methyl 4-methoxybenzoate, were brominated with PhSSiMe3 or PhSSPh and N-bromosuccinimide in high yields. No reaction was observed in the absence of PhSSiMe3 or PhSSPh. This method is also applicable to chlorination reactions using N-chlorosuccinimide and PhSSPh.

Product Details of 151-10-0. Welcome to talk about 151-10-0, If you have any questions, you can contact Hirose, Y; Yamazaki, M; Nogata, M; Nakamura, A; Maegawa, T or send Email.

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An article A Broad Substrate Scope of Aza-Friedel-Crafts Alkylation for the Synthesis of Quaternary alpha-Amino Esters WOS:000562077400022 published article about ACIDS; CONFORMATIONS; ALKYNYLATION; ACTIVATION; DISCOVERY; CATALYSIS; PEPTIDES; STRATEGY; BINDING; DESIGN in [Zhao, Guangkuan; Samanta, Shyam S.; Michieletto, Jessica; Roche, Stephane P.] Florida Atlantic Univ, Dept Chem & Biochem, Boca Raton, FL 33431 USA; [Roche, Stephane P.] Florida Atlantic Univ, Ctr Mol Biol & Biotechnol, Jupiter, FL 33458 USA in 2020, Cited 65. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0. Quality Control of 1,3-Dimethoxybenzene

A versatile synthetic protocol of aza-Friedel-Crafts alkylation has been developed for the synthesis of quaternary alpha-amino esters. This operationally simple alkylation proceeds under ambient conditions with high efficiency, regioselectivity, and an exceptionally broad scope of arene nucleophiles. A key feature of this alkylation is the role associated with the silver(I) salt counteranions liberated during the reaction. Taking advantage of a phase-transfer counteranion/Bronsted acid pair mechanism, we also report a catalytic enantioselective example of the reaction.

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Strojnik, L; Grebenc, T; Ogrinc, N in [Strojnik, Lidija; Ogrinc, Nives] Jogef Stefan Inst, Dept Environm Sci, Ljubljana 1000, Slovenia; [Strojnik, Lidija; Ogrinc, Nives] Jogef Stefan Int Postgrad Sch, Ljubljana 1000, Slovenia; [Grebenc, Tine] Slovenian Forestry Inst, Dept Forest Physiol & Genet, Ljubljana 1000, Slovenia published Species and geographic variability in truffle aromas in 2020, Cited 23. SDS of cas: 151-10-0. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0.

The gastronomic relevance and price of truffles are related mainly to its unique aroma. In this study, we explore the impact that different volatile compounds have on the aroma quality of fresh truffles using gas chromatography-mass spectrometry (GC-MS). Four hundred sixty fresh ascocarps of nine truffle species (Tuber aestivum, Tuber magnatum, Tuber melanosporum, Tuber mesentericum, Tuber brumale, Tuber excavatum, Tuber rufum, Tuber indicum and Tuber macrosporum) harvested in 2018/19 and 2019/2020 from 11 different countries (Slovenia, Croatia, Bosnia in Herzegovina, Macedonia, Italy, Spain, France, United Kingdom, Germany, Poland and China) were collected. Our investigation included the classification of species based on their aroma profile, a study of the differences in the volatile organic composition of truffle species over a geographical area, and, in more detail, a study of T. aestivum from four natural truffle growing sites in Slovenia. Our models can distinguish between groups, with small classification error. These models could form the basis of a predictive framework to detect fraud concerning truffle products and to determine the influence of different growing parameters on the aroma profile of truffles.

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An article A simple method for the synthesis of sulfonic esters WOS:000550938700001 published article about ESTROGEN-RECEPTOR LIGANDS; CROSS-COUPLING REACTIONS; CONSTRAINED ANALOGS; PROTECTING GROUP; FACILE SYNTHESIS; ARYL TOSYLATES; ACID ESTERS; SULFONYLATION; CATALYST; PHENOLS in [Bhatthula, Bharath Kumar Goud; Kanchani, Janardhan Reddy; Arava, Veera Reddy] Suven Life Sci Ltd, Res & Dev Ctr, Hyderabad, India; [Kanchani, Janardhan Reddy; Marata Chenna Subbarao, Subha] Sri Krishnadevaraya Univ, Dept Chem, Anantapur, Andhra Pradesh, India in 2020, Cited 71. Name: 1,3-Dimethoxybenzene. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0

An efficient and simple approach for the direct synthesis of aryl and heteroaryl sulfonic esters was developed using DMS and DES as alkoxysulfonylation reagents. The reaction is operationally simple and scalable. This protocol does not require solvent, expensive catalysts, base, ligand additives or other reagents. A wide range of sulfonic esters were synthesized in moderate to good chemical yields. This method has the advantage of low cost, facile and tolerated a wide range of substrates.

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An article Ordered mesoporous silica-supported metal catalysts for hydrodeoxygenation of anisole derivatives WOS:000603360700004 published article about LIGNIN MODEL COMPOUNDS; BIOMASS-DERIVED LIGNIN; PYROLYSIS OIL; JET FUEL; SBA-16; CONVERSION; TRANSALKYLATION; TECHNOLOGIES; TEMPERATURE; ADSORPTION in [Szczyglewska, Paulina; Feliczak-Guzik, Agnieszka; Nowak, Izabela] Adam Mickiewicz Univ, Fac Chem, Dept Apllied Chem, Uniwersytetu Poznanskiego 8, PL-61614 Poznan, Poland in 2021, Cited 50. Formula: C8H10O2. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0

The aim of the study presented was a comprehensive analysis of catalytic performance of palladium and platinum catalysts (1 or 3 wt% relative to the support), on SBA-16, in hydrodeoxygenation (HDO) of chemical compounds generated in biomass processing (anisole, 4-methylanisole and 1,3-dimethoxybenzene). HDO of these compounds was carried out in a high pressure reactor for 4 h in temperatures from 90 to 130 degrees C and under hydrogen pressure of 25-60 bar. The catalytic performance of palladium and platinum modified materials was found to differ considerably. The SBA-16 supported catalyst modified with palladium permitted getting high conversion of the model molecules studied (often 100%), while those modified with platinum showed higher selectivity to the compounds with no oxygen atom in their structures, which allowed a significant reduction of the O/C ratio. Direct impact of the process conditions (temperature, pressure) on the degree of conversion and selectivity of the HDO process was established and characterized.

Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Formula: C8H10O2. In 2019 MENDELEEV COMMUN published article about HYDROGEN-BOND; INDOLE-DERIVATIVES; ALKYLATION; CATALYST; ACIDS; PYRROLES in [Feofanov, Mikhail N.; Averin, Alexei D.; Beletskaya, Irina P.] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia in 2019, Cited 36. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0.

The Friedel Crafts reaction between electron-rich (het)arenes and beta-nitrostyrenes under MgI2 or Ca(NTf2)(2) catalysis affords 1-(het)aryl-2-nitro-1-phenylethanes in yields up to 94%.

Formula: C8H10O2. Welcome to talk about 151-10-0, If you have any questions, you can contact Feofanov, MN; Averin, AD; Beletskaya, IP or send Email.

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Recommanded Product: 1,3-Dimethoxybenzene. In 2019 ORG LETT published article about C-H; STEREOSPECIFIC SYNTHESIS; ELECTROPHILIC AMINATION; CATALYZED AMINATION; BONDS in [Munnuri, Sailu; Anugu, Raghunath Reddy; Falck, John R.] Univ Texas Southwestern Med Ctr Dallas, Dept Biochem, Div Chem, Dallas, TX 75390 USA in 2019, Cited 32. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0.

Cu(II)-mediated direct NH2 and NH alkyl aryl aminations and olefin aziridinations are described. These room temperature, one-pot, environmentally friendly procedures replace costly Rh-2 catalysts and, in some instances, display important differences with comparable Rh-2- and Fe-supported reactions.

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Name: 1,3-Dimethoxybenzene. Recently I am researching about LEWIS-BASE CATALYSIS; SELECTIVE HALOGENATION; AROMATIC-COMPOUNDS; EFFICIENT; FUNCTIONALIZATION; BIOSYNTHESIS; BROMINATION; ACTIVATION; TRYPTOPHAN; EVOLUTION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21602005, 21632001, 81821004]; National Basic Research Program of China (973 Program)National Basic Research Program of China [2015CB856600]; Drug Innovation Major Project [2018ZX09711-001]; Open Fund of State Key Laboratory of Pharmaceutical Biotechnology, Nanjing University, China [KF-GN-201906]. Published in NATURE RESEARCH in BERLIN ,Authors: 20220118. The CAS is 151-10-0. Through research, I have a further understanding and discovery of 1,3-Dimethoxybenzene

The chlorination of a bioactive compound can change its physiological properties and improve its pharmacokinetic and pharmacological profiles. It therefore has been an important strategy for drug discovery and development. However, the direct aromatic chlorination of complex bioactive molecules is too difficult to be practical. In fact, many functional groups such as hydroxyls, amines, amides or carboxylic acids may strongly restrain the reactivity of Cl+ by forming a halogen bond. Here we report a highly efficient aromatic chlorination of arenes that is catalysed by dimethyl sulfoxide with N-chlorosuccinimide as the chloro source. The mild conditions, easy-availability and stability of the catalyst and reagents, as well as good functional-group tolerance, showed the approach to be a versatile protocol for the late-stage aromatic chlorination of complex natural products, drugs and peptides. The multi-gram experiment and low-cost of N-chlorosuccinimide and dimethyl sulfoxide shows great potential for drug discovery and development in industrial applications. Late-stage aromatic chlorination of active pharmaceutical ingredients has enormous potential in drug discovery yet still features limited applicability due to issues of functional-group tolerance. Now, dimethyl sulfoxide is reported as catalyst for the chlorination of a diverse family of bioactive molecules in combination with N-chlorosuccinimide.

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In 2021 SYNTHESIS-STUTTGART published article about C-H BOND; ANTRODIA-CAMPHORATA; SELECTIVE SYNTHESIS; MICHAEL ADDITION; CYCLIC IMIDES; DERIVATIVES; INDOLES; 1,4-ADDITION; CONSTRUCTION; ALKYLATION in [Gairola, Deepti; Peddinti, Rama Krishna] Indian Inst Technol Roorkee, Dept Chem, Roorkee 247667, Uttarakhand, India in 2021, Cited 49. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0. Name: 1,3-Dimethoxybenzene

Friedel-Crafts reaction is widely used for the C-C bond forming reaction to enable the direct connection of electron-rich arenes to electron-deficient olefins with high regioselectivity. Herein, a highly efficient, metal-free, and environmentally benign F-C strategy of electron-rich arenes with N-arylmaleimides has been developed for the construction of 3-arylsuccinimides in the presence of a green reagent methanesulfonic acid under mild reaction conditions. This highly facile and high-yielding protocol has compatibility with different electron-rich arenes.

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An article One-pot access to 2-amino-3-arylbenzofurans: direct entry to polyheterocyclic chemical space WOS:000580494600012 published article about OPTICAL-PROPERTIES; DERIVATIVES; INDOLIZINE; HYBRIDS; DESIGN in [Kim, Ikyon] Yonsei Univ, Coll Pharm, 85 Songdogwahak Ro, Incheon 21983, South Korea; Yonsei Univ, Yonsei Inst Pharmaceut Sci, 85 Songdogwahak Ro, Incheon 21983, South Korea in 2020, Cited 41. The Name is 1,3-Dimethoxybenzene. Through research, I have a further understanding and discovery of 151-10-0. Computed Properties of C8H10O2

As a means to make new benzofuran-embedded polycyclic structures, we established two efficient one-pot sequential coupling routes to 2-amino-3-arylbenzofurans and 2-amino-3-arylnaphtho[2,1-b]furans. Further ring formation (six- and seven-membered rings) with the resulting amine moiety at the C2 position of benzofurans was realized, leading to further expansion of benzofuran-based chemical space.

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