Category: 99-04-7

I found the field of Chemistry very interesting. Saw the article Fe(III)-catalyzed oxidative coupling of alkylnitriles with aromatic carboxylic acids: Facile access to cyanomethyl esters published in 2019. Formula: C8H8O2, Reprint Addresses Sun, HM (corresponding author), Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China.. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid

The first oxidative coupling of alkylnitriles with aromatic carboxylic acids using di-tert-butyl peroxide (DTBP) as oxidant was achieved under the catalysis of ionic Fe(III) complexes bearing an imidazolinium cation. This protocol features nontoxic iron catalysis, direct alpha-C(sp(3))-H bond oxidative esterification of alkylnitriles, non-prefunctionalized starting materials, and a broad substrate scope with outstanding steric hindrance tolerance, providing a novel, straightforward, and green approach toward cyanomethyl ester synthesis. (C) 2019 Elsevier Ltd. All rights reserved.

Formula: C8H8O2. About 3-Methylbenzoic acid, If you have any questions, you can contact Wang, D; Lu, B; Song, YL; Sun, HM; Shen, Q or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

An article Estimation of vapor pressures of liquid and solid organic and organometallic compounds at 298.15 K WOS:000542072400002 published article about STRUCTURE-PROPERTY RELATIONSHIPS; THERMOCHEMICAL PROPERTIES; THERMODYNAMIC PROPERTIES; VAPORIZATION ENTHALPIES; PARTITION-COEFFICIENTS; AQUEOUS SOLUBILITY; PREDICTION; SUBLIMATION; ACIDS; ALKYL in [Abraham, Michael H.] UCL, Dept Chem, 20 Gordon St, London WC1H OAJ, England; [Acree, William E., Jr.] Univ North Texas, Dept Chem, POB 305070, Denton, TX 76203 USA in 2020, Cited 77. Computed Properties of C8H8O2. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7

Equations for vapor pressure VP, as log VP, at 298.15 K for a set of 1016 liquid organic and organometallic compounds have been constructed using Abraham descriptors. The regression standard deviations of 0.28 and 0.31 log units are excellent by comparison with literature values for large data sets. Similar equations for a set of 359 solid organic and organometallic compounds were very poor, but if carboxylic acids were excluded we obtained equations for 261 compounds with standard deviations of 0.62 and 0.66 log units. For the 98 carboxylic acids taken separately we obtained equations with standard deviations of 0.84 and 0.91 log units. Equations for the carboxylic acids were substantially different to those that excluded carboxylic acids, due, we suggest, to the particular dimeric structure of the crystalline carboxylic acids. (C) 2020 Published by Elsevier B.V.

About 3-Methylbenzoic acid, If you have any questions, you can contact Abraham, MH; Acree, WE or concate me.. Computed Properties of C8H8O2

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

HPLC of Formula: C8H8O2. In 2020 ORG LETT published article about FUNCTIONALIZATION; PALLADIUM; ARYLATION; BONDS; OLEFINATION; ARYL; ARENES; AMIDATION; AMINATION; ESTERS in [Li, Jian-Jun; Wang, Cheng-Gang; Yu, Jin-Feng; Wang, Peng] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Ctr Excellence Mol Synth, Shanghai 200032, Peoples R China; [Wang, Peng] Shanghai Inst Organ Chem, CAS Key Lab Energy Regulat Mat, Shanghai 200032, Peoples R China; [Yu, Jin-Quan] Scripps Res Inst, La Jolla, CA 92037 USA in 2020, Cited 53. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.

An efficient Cu-catalyzed C-H alkenylation with acyclic and cyclic vinyl boronates was realized for the first time under mild conditions. The scope of the vinyl borons and the compatibility with functional groups including heterocycles are superior than Pd-catalyzed C-H coupling with vinyl borons, providing a reliable access to multisubstituted alkenes and dienes. Subsequent hydrogenation of the product from the internal vinyl borons will lead to installation of secondary alkyls.

HPLC of Formula: C8H8O2. About 3-Methylbenzoic acid, If you have any questions, you can contact Li, JJ; Wang, CG; Yu, JF; Wang, P; Yu, JQ or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Formula: C8H8O2. In 2019 CHEM LETT published article about FLUORIDE-MEDIATED CARBOXYLATION; C-H SILYLATION; ESTERS; CO2; REAGENTS; ALKYNES in [Yoo, Woo-Jin; Kobayashi, Shu] Univ Tokyo, Grad Sch Sci, Green & Sustainable Chem Cooperat Lab, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan; [Kondo, Junpei; Kobayashi, Shu] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan in 2019, Cited 35. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.

A mild synthetic protocol for the preparation of aryl and alkenyl carboxylic acids was developed through a copper-catalyzed carboxylation reaction of organosilanes with carbon dioxide. The key to this process was the fine-tuning of the reactivity and selectivity of the organometallic nucleophile through structural modifications of the silane.

Formula: C8H8O2. About 3-Methylbenzoic acid, If you have any questions, you can contact Yoo, WJ; Kondo, J; Kobayashi, S or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Recommanded Product: 3-Methylbenzoic acid. Kumar, M; Verma, S; Verma, AK in [Kumar, Manoj; Verma, Shalini; Verma, Akhilesh K.] Univ Delhi, Dept Chem, Delhi 110007, India published Ru(II)-Catalyzed Oxidative Olefination of Benzamides: Switchable Aza-Michael and Aza-Wacker Reaction for Synthesis of Isoindolinones in 2020.0, Cited 65.0. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.

Selective tandem oxidative C-H olefination-azaMichael/aza-Wacker reaction of N-arylbenzamides is achieved by fine-tuning between base and additive to access valuable 3-oxoisoindolinyls and 3-oxoisoindolinylidenes, respectively. Careful optimization and control experiments provides a guiding principle in the design of a proposed catalytic cycle. The copper-iminium complex acting as a precursor for the binding of Ru catalyst was isolated and confirmed by X-ray diffraction. The versatility of this catalytic system has been demonstrated by the synthesis of biologically relevant molecules.

About 3-Methylbenzoic acid, If you have any questions, you can contact Kumar, M; Verma, S; Verma, AK or concate me.. Recommanded Product: 3-Methylbenzoic acid

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Authors Chen, HH; Hao, SL; Chen, Z; O-Thong, S; Fan, JJ; Clark, J; Luo, G; Zhang, SC in PERGAMON-ELSEVIER SCIENCE LTD published article about DISSOLVED ORGANIC-MATTER; RESOLUTION MASS-SPECTROMETRY; GEN. NOV.; BIO-OIL; PRODUCTS; WASTE; DEGRADATION; TEMPERATURE; WATER; TRANSFORMATION in [Chen, Huihui; Hao, Shilai; Chen, Zheng; Luo, Gang; Zhang, Shicheng] Fudan Univ, Dept Environm Sci & Engn, Shanghai Key Lab Atmospher Particle Pollut & Prev, Shanghai 200433, Peoples R China; [Hao, Shilai] Colorado Sch Mines, Dept Civil & Environm Engn, Golden, CO 80401 USA; [O-Thong, Sompong] Thaksin Univ, Fac Sci, Dept Biol, Phathalung 93110, Thailand; [Fan, Jiajun; Clark, James] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England; [Luo, Gang; Zhang, Shicheng] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China in 2020.0, Cited 51.0. HPLC of Formula: C8H8O2. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7

The critical challenge of hydrothermal liquefaction (HTL) for bio-oil production from biomass is the production of large amounts of aqueous products (HTL-AP) with high organic contents. The present study investigated the anaerobic digestion (AD) performances of HTL-AP under both thermophilic and mesophilic conditions, and molecular and metabolic analysis were conducted to provide insights into the different performances. The results showed that thermophilic AD had lower COD removal efficiency compared to mesophilic AD (45.0% vs. 61.6%). Liquid chromatography coupled with organic carbon detection and organic nitrogen (LC-OCD-OND) analysis showed that both high molecular weight (HMW) and low molecular weight (LMW) compounds were degraded to some extent and more LMW acids (LMWA) and recalcitrant aromatic compounds were degraded in the mesophilic reactor, which was the main reason of higher COD removal efficiency. Phenyl compounds (e.g. phenol and 2 methoxyphenol), furans and pyrazines were the recalcitrant chemicals detected through GC-MS analysis. Fourier transform ion cyclone resonance mass spectrometry (FT-ICR-MS) analysis demonstrated the complexity of HTL-AP and the proportions of phenolic or condensed aromatic compounds increased especially in the thermophilic effluents. Metabolites analysis showed that the reasons contributing to the differences of mesophilic and thermophilic AD were not only related to the degradation of organic compounds (e.g. benzoate degradation via CoA ligation) in HTL-AP but also related to the microbial autogenesis (e.g. fatty acid biosynthesis) as well as the environmental information processing. In addition, the enrichment of Mesotoga, responsible for the high degradation efficiency of LMWA, and Pelolinea, involved in the degradation of phenyl compounds, were found in mesophilic reactor, which was consistent with higher removal of corresponding organics. (C) 2019 Elsevier Ltd. All rights reserved.

About 3-Methylbenzoic acid, If you have any questions, you can contact Chen, HH; Hao, SL; Chen, Z; O-Thong, S; Fan, JJ; Clark, J; Luo, G; Zhang, SC or concate me.. HPLC of Formula: C8H8O2

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Authors Bera, S; Mondal, P; Sarkar, D; Pathi, VB; Pakrashy, S; Datta, A; Banerji, B in AMER CHEMICAL SOC published article about CROSS-COUPLING REACTIONS; C BOND FORMATION; ALPHA-PYRONES; METAL CARBENE; DENSITY FUNCTIONALS; BASIS-SETS; ISOCOUMARINS; ARYLATION; TOSYLHYDRAZONES; INSERTION in [Bera, Suvankar; Sarkar, Debabrata; Pathi, Vijay Babu; Pakrashy, Sourav; Banerji, Biswadip] Indian Inst Chem Biol CSIR IICB, Organ & Med Chem Div, Kolkata 700032, India; [Mondal, Partha; Datta, Ayan] Indian Assoc Cultivat Sci, Sch Chem Sci, Kolkata 700032, India; [Banerji, Biswadip] Indian Inst Chem Biol CSIR IICB, Acad Sci & Innovat Res AcSIR, Kolkata 700032, India in 2021, Cited 67. SDS of cas: 99-04-7. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7

A Rh(III)-catalyzed regioselective redox-neutral cascade process of carbenoid functionalization followed by dephosphonylative annulation of benzoic acids with alpha-diazo-beta-keto phosphonate has been realized, which led to the direct synthesis of a privileged 3-substituted isocoumarin scaffold. To the best of our knowledge, this is the first report of a complete redox neutral method to synthesize isocoumarins using C-H functionalization strategy. In the catalytic cycle of this reaction, there are two possible pathways for the C-C coupling between ortho-positioned carbon atom of benzoic acid and the diazo carbon atom: (i) concerted 1,2-aryl shift and (ii) stepwise metal-carbene formation followed by migratory insertion. DFT study has predicted that the concerted pathway has lower activation energy as compared to the stepwise pathway by 1.5 kcal/mol.

SDS of cas: 99-04-7. About 3-Methylbenzoic acid, If you have any questions, you can contact Bera, S; Mondal, P; Sarkar, D; Pathi, VB; Pakrashy, S; Datta, A; Banerji, B or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Huang, C; Zhu, KF; Zhang, YY; Lu, GZ; Shao, ZC; Gao, K; Mi, LW; Hou, HW in [Huang, Chao; Zhu, Kaifang; Zhang, Yingying; Lu, Guizhen; Mi, Liwei] Zhongyuan Univ Technol, Ctr Adv Mat Res, Zhengzhou 450007, Henan, Peoples R China; [Shao, Zhichao; Gao, Kuan; Hou, Hongwei] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China published Surfactant-assisted assembly of nanoscale zinc coordination compounds to enhance tandem conversion reactions in water in 2019, Cited 62. Application In Synthesis of 3-Methylbenzoic acid. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.

Precise control over the morphology and size of coordination polymers (CPs) is crucial for extending these inorganic-organic materials to many advanced applications, in particular for heterogeneous catalysis. In this work, two Zn-based CPs, {[Zn-3(idbt)(2)(4,4 ‘-dmbpy)(2)]center dot H2O}(n) (1) and {[Zn-3(idbt)(2)(H2O)(3)]center dot H2O}(n) (2) (H(3)idbt = 5,5 ‘-(1H-imidazole-4,5-diyl)-bis-(2H-tetrazole), 4,4 ‘-dmbpy = 4,4 ”-dimethyl-2,2 ‘-bipyridine), were synthesized through solvothermal reactions. The morphologies and particle sizes of 1 and 2 could be controlled from large scale to nanoscale by regulating the amount of poly(vinyl alcohol) (PVA). Furthermore, for the conversion reactions of nitromethylbenzenes into benzoic acids, the catalytic properties of nanoscale 1 and 2 were much more efficient than those of large size of 1 and 2, because of the benefit of readily accessible active sites in the nanoscale sized particles, which provide a tunable and functionalizable platform for the conversion reaction by minimizing the diffusion distance but do little for the selectivity.

Application In Synthesis of 3-Methylbenzoic acid. About 3-Methylbenzoic acid, If you have any questions, you can contact Huang, C; Zhu, KF; Zhang, YY; Lu, GZ; Shao, ZC; Gao, K; Mi, LW; Hou, HW or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Product Details of 99-04-7. Recently I am researching about FACILE SYNTHESIS; DERIVATIVES; 1,3,4-THIADIAZOLE; ANTICANCER, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21262012]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2016CFB400]. Published in CHINESE JOURNAL STRUCTURAL CHEMISTRY in FUJIAN ,Authors: Song, XJ; Wang, XM; Sun, Q; Huang, ST; Wang, Y. The CAS is 99-04-7. Through research, I have a further understanding and discovery of 3-Methylbenzoic acid

N-(5-Aryl-1,3,4-thiadiazol-2-yl)-N’-((E)-styryl)ureas 4a similar to 4i were designed and synthesized as antitumor agents, and their structures were characterized by IR, H-1 NMR, C-13 NMR, MS and elemental analysis. The single crystal of compound 4a, C17H13FN4OS, was also determined by X-ray crystallography. Crystal data: monoclinic, space group P21/n, a = 4.9401(8), b = 8.7100(15), c = 36.604(6) angstrom, beta = 93.320(3)degrees, V = 1572.4(5) angstrom(3), Z = 4, F(000) = 704, D-c = 1.438 g/cm(3), mu = 0.228 mm(-1), R = 0.0600 and wR = 0.1448 for 2743 independent reflections (R-int = 0.0418) and 2174 observed ones (I > 2 sigma(I)). The in vitro antitumor activities of compounds 4a similar to 4i were preliminarily evaluated by the standard MTT assay.

About 3-Methylbenzoic acid, If you have any questions, you can contact Song, XJ; Wang, XM; Sun, Q; Huang, ST; Wang, Y or concate me.. Product Details of 99-04-7

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com

Recommanded Product: 3-Methylbenzoic acid. Zhou, X; Xu, HY; Yang, QD; Chen, H; Wang, SF; Zhao, HQ in [Zhou, Xi; Xu, Hongyan; Yang, Qiaodan; Chen, Hua; Zhao, Huaiqing] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Shandong, Peoples R China; [Wang, Shoufeng] Univ Jinan, Shandong Prov Key Lab Fluorine Chem & Chem Mat, Sch Chem & Chem Engn, Jinan 250022, Shandong, Peoples R China published Co(ii)/Cu(ii)-cocatalyzed oxidative C-H/N-H functionalization of benzamides with ketones: a facile route to isoindolin-1-ones in 2019, Cited 64. The Name is 3-Methylbenzoic acid. Through research, I have a further understanding and discovery of 99-04-7.

A cobalt and copper catalyzed reaction protocol has been developed to achieve the oxidative C-H/N-H annulation of benzamides containing an 8-aminoquinoline moiety as the directing group with ketones. Structurally diverse isoindolin-1-ones were furnished by the reaction of various substituent benzamides with ketones.

Recommanded Product: 3-Methylbenzoic acid. About 3-Methylbenzoic acid, If you have any questions, you can contact Zhou, X; Xu, HY; Yang, QD; Chen, H; Wang, SF; Zhao, HQ or concate me.

Reference:
Isothiazole – Wikipedia,
,Isothiazole – ScienceDirect.com